@proceedings {284, title = {Evidence for arsenic-mineralization in granitic basement rocks, Ayer Granodiorite, northeastern Massachusetts}, volume = {42}, year = {2010}, note = {Accession Number: 2010-100047; Conference Name: Geological Society of America, Northeastern Section, 45th annual meeting; Geological Society of America, Southeastern Section, 59th annual meeting; Baltimore, MD, United States; Conference Date: 20100314; Language: English; Coordinates: N420800N424400W0710200W0715300; Coden: GAAPBC; Collation: 1; Collation: 160; Publication Types: Abstract Only; Serial; Conference document; Updated Code: 201052; Monograph Title: Geological Society of America, Northeastern Section, 45th annual meeting; Geological Society of America, Southeastern Section, 59th annual meeting; joint meeting, abstracts volume; Monograph Author(s): Anonymous; Reviewed Item: Analytic}, month = {2010/03/01/}, pages = {160 - 160}, publisher = {Geological Society of America (GSA) : Boulder, CO, United States}, address = {United States}, abstract = {Core samples of the Ayer Granodiorite along the eastern margin of the Merrimack Belt in northeastern Massachusetts host a series of sulfide and oxide phases that resulted from interaction with sulfide-bearing meta-sedimentary host rocks. Euhedral arsenopyrite grains are found with ilmenite, apatite, and REE phosphates in zones that generally mimic the intersection between a gneissic fabric and a relict magmatic foliation. Arsenopyrite crystals are typically elongate with this lineation. Euhedral to subhedral pyrite crystals have also been observed, but are localized to areas without As-bearing phases. Micro-fractures that parallel either a steep NW-striking joint set or gently-dipping sheeting joints are commonly filled with interwoven calcite cements and As-bearing Fe-oxides. Surface coatings of major fracture sets are also characterized by Fe-As-rich rinds that host micron-scale sub-angular particles of quartz, feldspars, and phyllosilicates. Where micro-fractures are most concentrated, sulfide-bearing minerals are less common; however, subhedral to anhedral arsenopyrite grains do occur along some open micro-fractures. These crystals preserve lobate grain boundaries and are associated with As-bearing Fe-oxide-rich coatings along adjacent fractures. The presence of 1) pyrite, 2) arsenopyrite associated with phosphates, and 3) As-bearing fracture coatings suggests multiple stages of mineralization. We propose that intrusion-related fluid-rock interaction associated with heating of nearby sulfide-bearing schists of the Berwick Formation during Acadian orogenesis may have provided the necessary constituents for growth of sulfide phases in the Ayer. It appears that Late Devonian greenschist facies metamorphism and metasomatism led to mineralization that generated arsenopyrite and accompanying phosphates; however, the role of the cross-cutting Clinton Newbury Fault Zone as a conduit for hydrothermal fluids may also be important. Lower temperature As-bearing Fe-oxide and calcite coatings on open fractures surfaces may be associated with a change from lithostatic- to hydrostatic-pressures during post-glacial regional uplift. This mineralization appears to be synchronous with intense microfracturing that post-dates all other mineralization.}, keywords = {$\#$StaffPubs, acadian, arsenic, arsenides, arsenopyrite, Ayer Granodiorite, Berwick formation, fractured materials, geochemistry, granodiorites, Igneous and metamorphic petrology 05A, igneous rocks, lower Paleozoic, massachusetts, Merrimack Synclinorium, metals, metamorphic rocks, metamorphism, metasedimentary rocks, metasomatism, Middlesex County Massachusetts, migration of elements, mineralization, Mineralogy of non-silicates 01C, northeastern Massachusetts, orogeny, Paleozoic, plutonic rocks, pollutants, pollution, pyrite, sulfides, United States}, isbn = {00167592}, url = {https://gsa.confex.com/gsa/2010NE/finalprogram/abstract_169998.htm}, author = {Koteas, G. Christopher and Keskula, Anna J. and Stein, Carol L. and McTigue, David F. and Joseph P Kopera and Brandon, William C.} } @proceedings {297, title = {Geochemistry of gneisses and amphibolites in the Uchee Belt of western Georgia and eastern Alabama; an ACRES progress report}, volume = {32}, year = {2000}, note = {Accession Number: 2002-039126; Conference Name: Geological Society of America, Southeastern Section, 49th annual meeting; Charleston, SC, United States; Conference Date: 20000323; Language: English; Coordinates: N322800N322800W0845900W0845900; Coden: GAAPBC; Collation: 1; Collation: 31; Publication Types: Abstract Only; Serial; Conference document; Updated Code: 200214; Monograph Title: Geological Society of America, Southeastern Section, 49th annual meeting; Monograph Author(s): Anonymous; Reviewed Item: Analytic}, month = {2000/03/01/}, pages = {31 - 31}, publisher = {Geological Society of America (GSA) : Boulder, CO, United States}, address = {United States}, abstract = {Undergraduate students, high school teachers, and university faculty representing ACRES (Atlanta Consortium for Research in Earth Sciences) studied lineated gneiss (LG) exposed at Flat Rock Park (FRP) and vicinity in Columbus, GA, and Motts gneiss (MG) in eastern Alabama. The LG and MG are mineralogically and geochemically granitoidal lineated orthogneisses. They contain deformed mafic xenoliths, as well as aplitic, granitic and pegmatoidal dikes that cut the dominant lineation. Based on chemical analyses, the LG from FRP and the MG plot as granite on the IUGS diagrams and the Le Bas diagram. Similarity in incompatible trace element ratios (e.g., Zr/Nb) and highly evolved characteristics of aplite with respect to the host gneisses, indicate there is probably a genetic link between the MG and the FRP LG. These rocks are chemically distinct from other nearby felsic gneiss. Phenix City gneiss amphibolites from Lindsey Creek and North Highland Mills dam in Columbus were also analyzed for major and trace elements. These amphibolites are low K tholeiitic rocks with an island arc affinity and are similar to rocks from the area that have already been analyzed. The amphibolites show a wide range of fractionation (41 to 62 percent SiO (sub 2) ). Consistency in incompatible element ratios over a wide range of fractionation of some of the samples show a probable genetic relationship among the various amphibolites of Lindsey Creek. Future work should involve more extensive collecting and analysis of both felsic rocks and amphibolites in the Uchee belt. More time should also be spent describing the thin sections of the existing collection and comparing the REE patterns for the FRP, MG and other felsic rocks in the Uchee belt.}, keywords = {$\#$StaffPubs, Alabama, amphibolite, chemical composition, Columbus Georgia, dikes, Georgia, gneisses, Igneous and metamorphic petrology 05A, inclusions, intrusions, metamorphic rocks, Muscogee County Georgia, Uchee Belt, United States, xenoliths}, isbn = {00167592}, author = {Joseph P Kopera and Nicholas, Brian and Todd, Dave and Davison, Jeff and Hanley, Tom and Kar, Aditya and La Tour, Timothy E. and Edwards, Tonya} }